Organic Chemistry-II

Course Code2863Marks: 100Credits: 4Class Hours: 60Course Title:Organic Chemistry-IIExam Duration: 4 Hours1. Organic Acids and Bases: Concepts, inductive, mesomeric and structural effects affecting the acidity and basicity; acid and base catalysis.2.Aromatic Hydrocarbons: Source; structure and bonding in benzene; concept of aromaticity; Huckel’s rule, nomenclature and their preparations, disubstitution in benzene ring; orientation in benzene ring and its derivatives, activation and deactivation in aromatic disubstitution, mechanism of electrophilic substitution in aromatic rings: halogenation, nitration, sulfonation, Friedel-Crafts alkylation and acylation. Benzene derivatives.3.Polynuclear Aromatic Hydrocarbons: General methods of synthesis, reactions of naphthalene, anthracene, phenanthrene and their derivatives.4.Amines: Aliphatic and aromatic, nomenclature, preparation and reaction of amines, Hofmann amine degradation, separation of amines, nomenclature, preparation and reactions of diazonium salt, coupling reaction.5.Heterocyclic Compounds Containing One and Two Hetero atoms: Aromatic character, chemistry and structure of heterocyclic compounds -furan, pyrrole, thiophene and pyridine.6.Stereochemistry: A brief concept of stereoisomerism, geometric and optical isomerism, polarimetry, optical activity, molecular asymmetry, optical isomerism due to asymmetric carbon atoms, compounds with one and two or more asymmetric carbon atoms, racemic modification and their formation, resolution of racemic modifications.7.Bifunctional Compounds: Chemistry of 1, 3-dienes, α-β unsaturated carbonyl compounds, hydroxy ketones, 1, 2-and 1, 3 –diketones, keto-enol tautomerism.Books Recommended:1.Organic Chemistry, I. L. Finar, Vol I & II, Longmans.2.Advanced Organic Chemistry, B. S. Bahl and A. Bahl, S. Chand & Co. Ltd.3.Organic Chemistry, T.W.G. Solomons, Wiley.4.Organic Chemistry, W.H. Brown, C.S. Foote and B.L. Iverson Brooks Cole